Electrocaloric cooling over high device temperature span
نویسندگان
چکیده
Conventional cooling method consumes large amount of electricity and heavily relies on hydrofluorocarbon coolants, which are considered “super-greenhouse effect” gases. Electrocaloric (EC) demonstrates high energy efficiency, involves no evaporative coolant, is a promising next-generation technology. A safe operational temperature change the EC material currently limited to well below 10 K, devices for practical application scenarios need be able pump heat at over 20 K. Since 90s, device community has mostly focused fluid-based prototypes that employ an oscillatory moving liquid actively transfer regenerate heat; this approach proved successful in building gradient Recently, few solid-state pumps have emerged featuring direct cascade style. Discussion these two architectures, material, actual manufacture challenges should broad interest design efficient compact systems. utilization often proposed as environmentally benign, alternative conventional vapor compression As result, fabrication effective electrocaloric materials engineering attracted increasing attention community. However, adiabatic under operation field poses major challenge development, since real-world applications usually require span This perspective presents recent efforts devoted based active regeneration cascading approaches; both strategies achieved significant lift ~10 K with 2~3 The discussed work broadly applicable ubiquitous (VCC) technology been long criticized its release gases aggravates disastrous global warming, difficulty scale down individual personal or device-level cooling.1Shi J.Y. Han D.L. Li Z.C. Yang L. Lu S.G. Zhong Z.F. Chen J.P. Zhang Q.M. Qian X.S. zero-global-warming-potential, high-efficiency refrigeration.Joule. 2019; 3: 1200-1225Abstract Full Text PDF Scopus (109) Google Scholar Solid-state cooling, effect (ECE),2Mischenko A.S. Q. Scott J.F. Whatmore R.W. Mathur N.D. Giant thin-film PbZr0.95Ti0.05O3.Science. 2006; 311: 1270-1271Crossref PubMed (1190) Scholar, 3Neese B. Chu B.J. Wang Y. Furman E. Large ferroelectric polymers near room temperature.Science. 2008; 321: 821-823Crossref (817) 4Ma R.J. Z.Y. Tong K.W. Huber D. Kornbluh R. Ju Y.S. Pei Q.B. Highly electrostatic actuation.Science. 2017; 357: 1130-1134Crossref (183) magnetocaloric (MCE),5Franco V. Blázquez J.S. Ipus J.J. Law Moreno-Ramírez L.M. Conde A. Magnetocaloric effect: from research refrigeration devices.Prog. Mater. Sci. 2018; 93: 112-232Crossref (585) 6Kitanovski Energy materials.Adv. 2020; 10Crossref (101) 7Pecharsky V.K. Gschneidner Jr., K.A. magnetic refrigeration.J. Magn. 1999; 200: 44-56Crossref (1252) elastocaloric (eCE),8Tušek J. Engelbrecht Eriksen Dall'Olio S. Tušek Pryds N. regenerative pump.Nat. Energy. 2016; 1: 16134Crossref (185) 9Kabirifar P. Žerovnik Ah?in Ž. Porenta Brojan M. Elastocaloric cooling: state-of-the-art future designing devices.SV-JME. 65: 615-630Crossref (29) 10Snodgrass Erickson multistage refrigerator 28 k span.Sci. Rep. 9: 18532Crossref (17) 11Tušek Millán-Solsona Mañosa Vives Mikkelsen L.P. way cool efficiently.Adv. 2015; 5: 1500361Crossref (162) barocaloric (BCE),12Li Kawakita Ohira-Kawamura Sugahara T. H. Y.N. Kawaguchi S.I. Ohara et al.Colossal effects plastic crystals.Nature. 567: 506-510Crossref (128) Scholar,13Lloveras Aznar Barrio Negrier Popescu C. Planes Stern-Taulats Avramenko crystals neopentylglycol.Nat. Commun. 10: 1803Crossref (70) being studied alternatives VCC-based refrigeration. While refrigerant forced go through repeated evaporation condensation cycles VCC system heat, caloric make use latent phase transition regulated by external field, such electrical, magnetic, mechanical stress, pressure. In particular, wide attention, thanks electricity, relatively simple cooler architecture. ideal solution compact, chip-scale thermal management.1Shi Scholar,14Ožbolt Kitanovski Poredoš refrigeration: thermodynamics, state art perspectives.Int. Refrig. 2014; 40: 174-188Crossref (140) 15Kumar Thakre Jeong D.Y. Ryu J.H. Prospects phenomenon ceramics.J. Chem. 7: 6836-6859Crossref 16Zhang also pump.Science. 1094-1095Crossref (16) ECE denotes dipolar entropy (?S) inside certain dielectric response variation applied electric corresponding (?TECE) if perfect isothermal condition cannot maintained.3Neese Pronounced observed inorganic bulk perovskite-like ceramics, including PbZr0.95Ti0.05O3,2Mischenko BaTiO3,17Qian Ye H.J. Y.T. Gu H.M. X.Y. Randall C.A. range modified BaTiO3 ceramics.Adv. Funct. 24: 1300-1305Crossref (292) PbSc0.5Ta0.5O318Nair Usui Crossley Kurdi Guzmán-Verri G.G. Moya X. Hirose oxide multilayer capacitors range.Nature. 575: 468-472Crossref (77) Scholar; single (NH4)2SO419Crossley W. single-crystal ammonium sulfate.Philos. Trans. Math. Phys. Eng. 374: 20150313PubMed (Ba,Ca)(Zr,Ti)O320Liu Yan Q.F. Electro-caloric BCZT crystal.CrystEngComm. 20: 1597-1602Crossref copolymers terpolymers derived polyvinylidenefluoride (PVDF).3Neese Scholar,21Li Cheng Fang Z. Tunable dependence relaxor poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene terpolymer.Appl. Lett. 2011; 99: 052907Crossref (118) ceramics can processed into rigid thin films thickness about 5 ?m; most cases, come form structure ensure viable working mass whilst sufficiently low voltage.22Smith N.A.S. Rokosz M.K. Correia T.M. Experimentally validated finite element model ceramic structures.J. Appl. 116: 044511Crossref (10) Scholar,23Usui Ando Nair Effect inactive volume thermocouple measurements 0.9Pb(Mg1/3Nb2/3)O-3-0.1PbTiO(3).J. D 50: 424002Crossref order intensity not higher than 100 MV/m. polymers, other hand, display strength 350 Such generates greater larger change, example,10 MV/m.24Lu Enhancing polymer minor normal phase.Appl. 113: 153903Crossref (18) Scholar,25Chen Xu W.H. B.A. Towards pump-A exhibiting field.Appl. 113902Crossref (20) Compared their counterparts, exhibit specific power density, like they prepared structures.26Gu Craven Zhu W.Y. A.L. Yao S.C. chip device.Appl. 2013; 102: 122904Crossref Scholar,27Gu Simulation chip-size cooling-power density.Appl. 112901Crossref (43) nanofillers well-controlled geometry were dispersed matrix loading up 15 vol%, some nanocomposites reported survive much fields, even example, 30 (via differential scanning calorimetry (DSC) measurement) 150 MV/m.28Zhang G.Z. T.N. L.Q. Jiang S.L. Colossal room-temperature using nanostructured barium strontium titanates.ACS Nano. 7164-7174Crossref 29Qian Peng R.C. Shen Z.H. Xue F. Interfacial coupling boosts giant nanocomposites: situ characterization phase-field simulation.Adv. 31: e1801949PubMed 30Zhang Gadinski M.R. Haque M.A. Ferroelectric refrigeration.Adv. 27: 1450-1454Crossref (157) utilize (referred hereafter) needs (Figure 1A), simplest cycling behavior described Brayton cycle process 4 stages 1B).16Zhang Starting stage 1, (E = 0), dipoles within randomly oriented. When E0 (stage 1?2), align along field. holds constant initial instance rapidly increases ?TECE condition. Next, 2?3), while maintained, makes contact sink, so ejected sink toward equilibrium; decrease. (from 3?4), removed return disorder, exchange occurs process, drops ?TECE. Finally, 4?1, source absorbs source. increase returns original 1. scheme represents straightforward strategy pump, repeated, continuously transported (in opposite direction spontaneous transfer). Recent developments seen largely enhanced peak almost 50 DSC measurement),30Zhang however, impressive obtained very (>250 MV/m) approaching breakdown limit. Cooling body size, operated repeatedly. Analogous film capacitor applications, voltage normally set ~30% safely operable fields lead changes just 1~10 K1 current materials, whereas spans higher. There general produce (?Tdevice) Active recovery fluid solution; recently, there reports systems emerging employing structure. reviews unique but thermodynamically relevant approaches, a.k.a. (AHR) respectively. Performance-limiting factors vital further expansion discussed. AHR fluidic media, mature practice multiple caloric-based technologies, magnetocaloric, elastocaloric, thermoelectric systems.6Kitanovski Scholar,8Tušek Scholar,10Snodgrass function refrigerant, same time regenerator. referred (AMR) termed (AER) cooling. regenerator requires rather bulky system; general, porous bed periodically goes effect, voids flow part. housed sealed tube-shaped chamber equipped pumping apparatus, generator, connected sink. Figure 2A depicts schematic setup where four phases take place turn.31Plaznik U. Roži? Mali? Urši? Drnovšek Cilenšek Vrabelj Kutnjak Bulk 106: 043903Crossref (116) 32Tahavori Veje Lei Nielsen K.K. Computationally 2015 IEEE International Conference Control System, Computing Engineering (ICCSCE), 2015: 135-140Google 33Mugica I. Roy Poncet Bouchard Nesreddine Exergy analysis parallel-plate nanofluids.Entropy. 19: 464Crossref (11) First, held stationary dipole polarized heats up. Second, holds, pumped leave hot end, picking when passing material; exits regenerator, it enters exchanger rejected Third, stopped depolarized via removing field; back down. Fourth, fluid, pushed counter second stage, deposits cold exchanger, With on, systematically fluid. After operation, steady built up, media. Although either side must exceed ?TECE, worth noting between sides ends (and well) (see profile 2A). buildup (EC element) possesses anisotropic conductivity, a.k.a., orthogonal surrounding conduction dimension (i.e., direction) regenerator.34Reinecke B.N. Shan J.W. Suabedissen Cherkasova On conductivity magnetorheological suspensions.J. 104: 023507Crossref (65) Scholar,35Fang X.P. Xuan Y.M. Anisotropic fluids.Prog. Nat. 2009; 205-211Crossref (32) AER conveniently Brayton-like 2B). Potentially more thermodynamic Ericsson hybrid Brayton-Ericsson achievable,36Plaznik Numerical experimental analyses different regenerator.Appl. Therm. 59: 52-59Crossref (64) delicate manipulation distribution flow.37Kitanovski Plaznik New refrigeration.Int. 37: 28-35Crossref (40) Importantly, AER, each infinitesimally small part interacts neighboring ones oscillating subjected cycle. solid exists across continuous temperatures, resulting distinctive piece. paths overlap iso-field phases, differ processes. dashed, dotted, T-S graph shown 2B represent partially overlapping performed coldest, middle, hottest parts area enclosed specified indicates done drive piece AER:w=?s(Tc,E>0)sTh,E>0Tds??sTc,E=0sTh,E=0Tds(Equation 1) s refers Integration values entire results overall device:W=?wdm(Equation 2) dm cross-sectional slice whose calculated w. maximum capability Qc_max heating Qh_max defined. no-load end (Tsource) warmer (Tsink) theoretical (blue region 2B) using:Qc_max=??s(Tc,E=0)s(Tsource,E=0)Tdsdm(Equation 3) Tc lowest cycle, integration those pieces lower Tsource. Likewise, (red is:Qh_max=??s(Tsink,E>0)s(Th,E>0)Tdsdm(Equation 4) Th highest Tsink. regenerated Qh_reg Qc_reg blue regions 2C) refer exchanged body) purpose. essential build span. From point view, picks total (Qh_reg + Qh_max) rejects sink; during (Qc_reg Qc_max) stripped off flow, cooled absorb source; driven input W, ideally equal Qc_reg. Hence, we neglect hysteresis loss propel coefficient performance (COP) device, signifies efficiency refrigerator, as:COP=Qc_maxW(Equation 5) COP value equals COPCarnot Tc/(Th – Tc). degree achieving factor (?Tdevice/?TECE) 10. prediction real complicated, aside intrinsic capability, dependent specs parameters, choice coefficient, rate, on.38Tušek Prebil Dynamic (AMR): numerical optimization packed-bed AMR.Int. 34: 1507-1517Crossref (75) Scholar,39Guo Gao Yu Y.J. Santhanam Slippey Fedder G.K. McGaughey A.J.H. Design modeling micro-scale system.Int. Heat Mass Transfer. 72: 559-564Crossref (48) Back 1995, Sinyavsky AER-based packs scandium tantalite (PbSc0.5Ta0.5O3, PST) plates 0.3 mm (the weighs 400 g length 300 mm), hexane agent, ?Tdevice 12.7 1.85 MV/m 0.75 Hz, PST was stated study.40Sinyavsky Y.V. Brodyansky V.M. Experimental testing transparent body.Ferroelectrics. 1992; 131: 321-325Crossref (117) Scholar,41Sinyavskii refrigerators: low-temperature apparatus.Chem. Petrol. 1995; 295-306Crossref (26) cost 750 all implementation details revealed report. 2015, coworkers demonstrated stack ([Pb(Mg0.33Nb0.66)O3]0.9[PbTiO3]0.1) × 0.2 mm, experimentally 3.3 3.7 times ?TECE.31Plaznik prototype 2E) runs frequency silicone oil liquid. predicts reaching upon optimization, only marginally affected magnitude Torrelo al. achievement 13.0 K—the far (MLC). employs guide configuration better performance. optimized houses 128 PST-MLCs (16 columns 8 rows, MLC 10.6 7.6 0.5 38.4 115 mm. employed 15.8 MV/m, gives rise 2.2 0.125 Hz. Prediction 47.5 16.3 W (850 kg?1) projected, 5.5 K.42Torelló Lheritier Nouchokgwe Gérard Bouton O. Defay regenerator.Science. 370: 125-129Crossref (38) presence difficult applications; besides, mixing mitigates regeneration-induced lowers device.43Brown G.V. Magnetic temperature.J. 1976; 47: 3673-3680Crossref (767) provides achieve size. showed that, stainless-steel media (solid regenerator), transformed alternating displacement respect corresponded timely triggered (Figures 2D 2F).26Gu
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ژورنال
عنوان ژورنال: Joule
سال: 2021
ISSN: ['2542-4351', '2542-4785']
DOI: https://doi.org/10.1016/j.joule.2020.12.018